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Research Technical Services

Differential Calorimetry of Tracking

DSC

It Differential calorimetry of Tracking (DSC) it is the technique of Thermal Analysis used more frequently. This technique measures the changes of enthalpy of the samples due to changes in its physical properties and chemists depending on the temperature or the time. Is used to analyse and to study polymers as thermoplastic, thermostable or elastomers as well as metallic material stickers, alimentary, pharmaceutical, chemical products, and composites

Job request

In order to request the analysis of samples for DSC, you have to get yourselves with the staff responsible for the team in touch.

It be necessary to inform of the toxicity and precautions of storage of the samples. If they do not come to search, the surpluses of sample will be destroyed in the deadline of a week from the delivery of results.

The equipment

METTLER TOLEDO DSC822e

Year:
2002



Rank of temperatures:
RT until 700ºC
Speed of maxim warming:
100K/min
Resolution:
<0,04mW

METTLER TOLEDO TGA/DSC 1

Year:
2014
Maximum temperature of the oven:
1600ºC
Temperature accuracy:
±0.5ºC
Temperature accuracy:
±0.3ºC
Rank of weighing:
≤5g

SETARAM Setsys Evolution 16

Year:
2004
Rank of temperatures:
 RT until 1500ºC
Speed of maxim warming:
100K/min
Resolution:
0.4 μW

YOUR INSTRUMENTS Q2000

Rank of temperatures:
-180ºC until 725ºC
Reproductibility of the basis line:
± 10 μW
Resolution:
0.2 μW 

How does it work?

This technique measures the heat absorbed or given off by a sample when this undergoes a programme of temperatures. The DSC is a differential technique, the flow of heat is calculated from the difference of temperature of the sample with respect to a reference. The encapsulated sample and he references it (generally an empty capsule) they position about the sensor, placed in an oven with very precise control of the temperature.

Is created one programme of temperatures depending on the process to monitor (fusion, crystallisation, vitreous transition, curate...). In the case of a dynamic programme, it be necessary to specify the initial temperature, the final temperature and the speed to the one who is wanted to be made the warming or cooling (ºC/ minute). In the case of an isothermal programme, it be necessary to specify the temperature of the isotherm and its duration.

In the graph resulting from the analysis the flow of heat (mW) absorbed is represented or afterwards for the sample depending on the temperature or the time.

Applications / Practical cases

Examples of thermal processes that can be determined by Differential Calorimetry of Tracking:

  •  Behaviour of fusion 
  •  Crystallisation and nucleation 
  •  Polymorphism 
  •  Transitions liquid - crystal 
  •  Diagrams of phases and composition 
  •  Vitreous transitions 
  •  Reactivity
  •  Kinetics of reaction

More information:

The acquisition of the equipment MT Instruments Q2000 it has been co-financed for the Ministerio of Science, Innovación y Universidades across European Background of Regional Development (FEDER).

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