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Analysis of total organic carbon

TOC

The analysis of total organic carbon (TOC) allows for the determination of different types of carbon present in a sample.This is based on a catalytic oxidation of the sample at 680ºC and the subsequent analysis of the CO2 generated through an infrared detector.

Job request

In order to carry out an analysis, get in touch with the head of the UEA.

The toxicity and storage precautions of the samples must be reported.Once the report has been made, if nobody comes to collect the sample after a week, it will be destroyed.

The equipment

SHIMATZU TOC-VCSH Total Organic Carbon Analyzer

Year :
2005
Characteristics :
The device measures the organic, inorganic and total carbon of a sample.It is equipped with an auto-sampler with capacity of 93 vials of 24 mL.The measuring interval is 100ppb at 1000 mgC/L.

How does it work?

The different types of carbon contained in a sample can be determined:

Total Carbon: In the combustion of the sample, two products are obtained: water (which is vaporised and eliminated through condensation) and organic and inorganic carbon (that oxidise in CO2).The CO2 generated is measured through a non-dispersive infrared detector (NDIR).

Inorganic Carbon: The inorganic carbon of a sample is determined through the acidification of the sample with phosphoric acid.In this process, CO2 is formed and analysed using the NDIR detector.

Total Organic Carbon: This is calculated by the difference between the total carbon and the inorganic carbon.

Non-Purgeable Organic Carbon (NPOC): In samples where the inorganic carbon content is much higher than the organic content, the recommendation is to measure the NPOC.This is obtained from the previous acidification of the sample in order to eliminate all the IC, and later shaking it to eliminate all the purgeable organic carbon.Then the acidified and shaken sample is placed inside a combustion tube where it is oxidised to generate CO2.

Applications / Practical cases

TOC is a fast, accurate and direct measure of the total organic contents of a sample of water, since it does not depend on the state of initial oxidation of the material.Some of the applications for this technique are:

  • Evaluation of the pollutants of several surface and underground types of water.
  • Water quality indicators.
  • Indicator not specific to the quality of the water in industrial processes.

The sample volume required for analysis is 24 mL (filtered at 0.45 µm).

PARTICIPATION IN INTERCOMPARISON TEST

Participation in this rehearsal is a way of measuring the quality of the results through an external evaluation.

Around 15 laboratories on an international scale usually participate.This consists of the analysis of two samples of continental waters, giving results of the contents of TOC.

The STR have taken part in it since 2022 bringing the value of the TOC, always obtaining satisfactory results.

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