Ernest Ubasart, Irene Mustieles Marin, Juan Manuel Asensio, Gabriel Mencia, Ángela M. López- Vinasco, Cristina García-Simón, Iker del Rosal, Romuald Poteau,* Bruno Chaudret*, Xavi Ribas* "Supramolecular nanocapsules as two-fold stabilizers of outer-cavity sub-nanometric Ru NPs and inner-cavity ultra-small Ru clusters." Nanoscale Horizons 2022 (2022): -. Lorena Capdevila, Judith Sala, Lutz Ackermann, and Xavi Ribas "Nickel-catalyzed Csp2-OMe functionalization for chemoselective aromatic homologation en route to nanographenes." Chemistry-A European Journal Online Version (2022): -. C. Magallón, L. Griego, C. H. Hu, A. Company, X. Ribas, L. M. Mirica "Organometallic Ni(II), Ni(III), and Ni(IV) complexes relevant to carbon-carbon and carbon-oxygen bond formation reactions." Inorganic Chemistry Frontiers 9 (2022): 1016-1022. Pau Font, Xavi Ribas* "Fundamental Basis for Implementing Oxidant-Free Au(I)/Au(III) Catalysis." European Journal of Inorganic Chemistry 2021 (2021): 2556-2569. Ernest Ubasart, Cristina García-Simón, Míriam Pujals, Karam Asad, Nikos Chronakis, Teodor Parella and Xavi Ribas* "Straightforward supramolecular purification of C84 from a fullerene extract." Organic Chemistry Frontiers 8 (2021): 4101-4105. Ernest Ubasart, Oleg Borodin, Carles Fuertes-Espinosa, Youzhi Xu, Cristina García-Simón, Laura Gómez, Judit Juanhuix, Felipe Gándara, Inhar Imaz, Daniel Maspoch, Max von Delius and Xavi Ribas "A Three-shell supramolecular complex enables the symmetry-mismatched chemo- and regioselective bis-functionalization of c60." Nature Chemistry (2021): -. Carla Magallón; Oriol Planas; Steven Roldán-Gómez; Josep M. Luis; Anna Company; Xavi Ribas "Well-Defined Aryl-FeII Complexes in Cross-Coupling and C-H Activation Processes." Organometallics 40 (2021): 1195-1200. Comas F; Latorre J; Ortega F; Arnoriaga-Rodríguez M; Lluch A; Sabater M; Rius F; Ribas X; Costas M; Ricart W; Lecube A; Fernández-Real JM; Moreno-Navarrete JM "Morbidly obese subjects show increased serum sulfide in proportion to fat mass." International Journal of Obesity 45 (2021): 415-426. Carles Fuertes-Espinosa, Míriam Pujals, Xavi Ribas "Supramolecular Purification and Regioselective Functionalization of Fullerenes and Endohedral Metallofullerenes." Chem 6 (2020): 3219-3262. Xavi Ribas, Raül Xifra, Xavier Fontrodona "Bis-Phenoxo-CuII2 Complexes: Formal Aromatic Hydroxylation via Aryl-CuIII Intermediate Species." Molecules 25 (2020): 4595-. Valentin Müller, Debasish Ghorai, Lorena Capdevila, Antonis M. Messinis, Xavi Ribas, Lutz Ackermann "C−F Activation for C(sp2)−C(sp3) Cross-Coupling by a Secondary Phosphine Oxide (SPO)-Nickel Complex." Organic Letters 22 (2020): 7034-7040. Cristina García-Simón; Cédric Colomban; Yarkin Aybars Çetin; Ana Gimeno; Míriam Pujals, Ernest Ubasart; Carles Fuertes-Espinosa; Karam Asad; Nikos Chronakis; Miquel Costas; Jesús Jiménez-Barbero*; Ferran Feixas*; Xavi Ribas* "Complete dynamic reconstruction of C60, C70, and (C59N)2 encapsulation into an adaptable supramolecular nanocapsule." Journal of the American Chemical Society 142 (2020): 16051-16063. Carles Fuertes-Espinosa; Cristina García-Simón; Míriam Pujals; Marc Garcia-Borràs; Laura Gómez; Teodor Parella; Judit Juanhuix; Inhar Imaz; Daniel Maspoch; Miquel Costas; Xavi Ribas* "Supramolecular Fullerene Sponges as Catalytic Masks for Regioselective Functionalization of C60." Chem 6 (2020): 169-186. Marco Cianfanelli; Giorgio Olivo; Michela Milan; Robertus J. M. Klein Gebbink; Xavi Ribas; Massimo Bietti; and Miquel Costas "Enantioselective C−H lactonization of unactivated methylenes directed by carboxylic acids." Journal of the American Chemical Society 142 (2019): 1584-1593. Melody Chu, Oriol Planas, Anna Company, Xavi Ribas, Alex Hamilton, Christopher J. Whiteoak "Unravelling the Mechanism of Cobalt-Catalysed Remote C-H Nitration of 8-Aminoquinolinamides and Expansion of Substrate Scope Towards 1-naphthylpicolinamide." Chemical Science 11 (2019): 534-542. Youzhi Xu, Sebastian Gsänger, Martin B. Minameyer, Inhar Imaz, Daniel Maspoch, Oleksandr Shyshov, Fabian Schwer, Xavi Ribas, Thomas Drewello, Bernd Meyer,* Max von Delius* "Highly Strained, Radially π‑Conjugated Porphyrinylene Nanohoops." Journal of the American Chemical Society (2019): -. Carles Fuertes-Espinosa, Jesse Murillo, Marco E. Soto, Maira R. Ceron, Roser Morales-Martínez, Antonio Rodríguez-Fortea, Josep M. Poblet, Luis Echegoyen,* Xavi Ribas* "Highly selective encapsulation and purification of U-based C78-EMFs within a supramolecular nanocapsule." Nanoscale 11 (2019): 23035-23041. Lorena Capdevila; Tjark H. Meyer; Steven Roldán-Gómez; Josep M. Luis; Lutz Ackermann; Xavi Ribas "Chemo-Divergent Nickel(0)-Catalyzed Arene C-F Activation with Alkynes: Unprecedented C-F/C-H Double-Insertion." ACS Catalysis 9 (2019): 11074-11081. Sofia M. Smith, Oriol Planas, Laura Gómez, Nigam P. Rath, Xavi Ribas, Liviu M. Mirica "Aerobic C-C and C-O bond formation reactions mediated by high-valent nickel species." Chemical Science 10 (2019): 10366-10372. Comas F; Latorre J; Cussó O; Ortega F; Lluch A; Sabater M; Castells-Nobau A; Ricart W; Ribas X; Costas M; Fernández-Real JM; Moreno-Navarrete JM "Hydrogen sulfide impacts on inflammation-induced adipocyte dysfunction." Food and Chemical Toxicology 131 (2019): 110543-. Urbanová, K.; Ramírez-Macías, I.; Martín-Escolano, R.; Rosales, M.-J.; Cussó, O.; Serrano, J.; Company, A.; Sánchez-Moreno, M.; Costas, M.; Ribas, X.; Marín, C. "Effective Tetradentate Compound Complexes against Leishmania spp. that Act on Critical Enzymatic Pathways of These Parasites." Molecules 24 (2018): 134-. García-Simón, C.; Monferrer, A.; Garcia-Borràs, M.; Imaz, I.; Maspoch, D.; Costas M.; Ribas. X. "Size-selective encapsulation of C60 and C60-derivatives within an adaptable naphthalene-based tetragonal prismatic supramolecular nanocapsule." Chemical Communications (2018): -. Lorena Capdevila; Erik Andris; Anamarija Briš; Màrius Tarrés; Steven Roldán-Gómez; Jana Roithová*; Xavi Ribas* "Silver(I)-Catalyzed C−X, C−C, C−N, and C−O Cross-Couplings Using Aminoquinoline Directing Group via Elusive Aryl-Ag(III) Species." ACS Catalysis 8 (2018): 10430-10436. Carla Magallón, Joan Serrano-Plana, Steven Roldán-Gómez, Xavi Ribas, Miquel Costas, Anna Company "Preparation of a coordinatively saturated μ-η2:η2-peroxodicopper(II) compound." Inorganica Chimica Acta 481 (2018): 166-170. Civan Avci, Amirali Yazdi, Marius Tarrés, Elise Bernoud, Neus G. Bastús, Víctor F. Puntes, Inhar Imaz, Xavi Ribas, and Daniel Maspoch "Sequential Deconstruction−Reconstruction of Metal−Organic Frameworks: An Alternative Strategy for Synthesizing (Multi)- Layered ZIF Composites." ACS Applied Materials and Interfaces 10 (2018): 23952-23960. Carles Fuertes‐Espinosa; Alejandra Gómez‐Torres; Roser Morales‐Martínez; Dr. Antonio Rodríguez‐Fortea; Dr. Cristina García‐Simón; Dr. Felipe Gándara; Dr. Inhar Imaz; Dr. Judith Juanhuix; Prof. Da "Purification of Uranium‐based Endohedral Metallofullerenes (EMFs) by Selective Supramolecular Encapsulation and Release." Angewandte Chemie International Edition (2018): -. O. Planas; S. Roldan-Gomez; V. Martin-Diaconescu; J. M. Luis; A. Company: X. Ribas "Mechanistic insights into the SN2-type reactivity of aryl-Co(III) masked-carbenes for C-C bond forming transformations." Chemical Science 9 (2018): 5736-5746. Jordi Serra; Pau Font; Eric Daiann Sosa Carrizo; Sonia Mallet-Ladeira; Stephane Massou; Teodor Parella; Karinne Miqueu; Abderrahmane Amgoune; Xavi Ribas; Didier Bourissou "Cyclometalated gold(III) complexes: noticeable differences between (N,C) and (P,C) ligands in migratory insertion." Chemical Science 9 (2018): 3932-3940. Cédric Colomban; Carles Fuertes-Espinosa; Sébastien Goeb; Marc Sallé; Miquel Costas; Lluis Blancafort; Xavi Ribas "Self-assembled Cofacial Zinc Porphyrin Supramolecular Nanocapsules as tuneable 1O2 Photosensitizers." Chemistry-A European Journal 24 (2018): 4371-4381. Oriol Planas, Paula G. Chirila, Christopher J. Whiteoak,* Xavi Ribas* "Current Mechanistic Understanding of Cobalt-Catalyzed C-H Functionalization." Advances in Organometallic Chemistry 69 (2018): 209-282. Cédric Colomban, Vlad Martin-Diaconescu, Teodor Parella, Sébastien Goeb, Cristina García-Simón, Julio Lloret-Fillol, Miquel Costas,* Xavi Ribas* "Design of Zn‑, Cu‑, and Fe-Coordination Complexes Confined in a 2 Self-Assembled Nanocage." Inorganic Chemistry 57 (2018): 3529-3539. Xavi Ribas, Marc Devillard "Model Macrocyclic Ligands for Proof-of-Concept Mechanistic Studies in Transition-Metal Catalysis." Chemistry-A European Journal 24 (2017): 1222-1230. Oriol Planas; Steven Roldan-Gomez; Vlad Martin-Diaconescu; Teodor Parella; Josep Maria Luis; Anna Company; Xavi Ribas "Carboxylate-Assisted Formation of Aryl-Co(III) Masked-Carbenes in Cobalt-Catalyzed C-H Functionalization with Diazo Esters." Journal of the American Chemical Society 139 (2017): 14649-14655. Mireia Rovira, Steven Roldán-Gómez, Vlad Martin-Diaconescu, Christopher J. Whiteoak, Anna Company, Josep M. Luis, Xavi Ribas "Trifluoromethylation of a Well-Defined Square-Planar Aryl-NiII Complex involving NiIII/CF3C and NiIV-CF3 Intermediate Species." Chemistry-A European Journal 23 (2017): 11662-11668. Rovira Coll, Mireia ; Jašíková, Lucie ; Andris, Erik ; Acuña-Parés, Ferran ; Soler, Marta ; Güell Costa, Imma ; Wang, Ming Zheng ; Gómez Martín, Laura ; Luis Luis, Josep Maria ; Roithová, Jana ; Ribas Salamaña, Xavi "A CuI/CuIII prototypical organometallic mechanism for the deactivation of an active pincer-like CuI catalyst in Ullmann-type couplings." Chemical Communications 53 (2017): 8786-8789. Fuertes-Espinosa C., García-Simón C., Castro E., Costas M., Echegoyen L. and Ribas X. "A Copper-based Supramolecular Nanocapsule that Enables Straightforward Purification of Sc3 N-based Endohedral Metallofullerene Soots." Chemistry-A European Journal 23 (2017): 3553-3557. Olaf Cussó; Michael W. Giuliano; Xavi Ribas; Scott J. Miller; Miquel Costas "A Bottom up Approach Towards Artificial Oxygenases by Combining Iron Coordination Complexes and Peptides." Chemical Science 8 (2017): 3660-3667. Colomban, C.; Szalóki, G.; Allain, M.; Gómez, L.; Goeb, S.; Sallé, M.; Costas, M.; Ribas, X. "Reversible C60 Ejection from a Metallocage through the Redox-Dependent Binding of a Competitive Guest." Chemistry-A European Journal (2017): -. Elise Bernoud, Anna Company*, Xavi Ribas* "Direct use of CO2 for O-arylcarbamate synthesis via mild Cu(II)- catalyzed aerobic C-H functionalization in pincer-like macrocyclic systems." Journal of Organometallic Chemistry 845 (2017): 44-48. Adarsh, N. N.; Chakraborty, Amarnath; Tarrés, Màrius; Dey, Surjendu; Novio, Fernando; Chattopadhyay, Basab; Ribas Salamaña, Xavi; Ruiz Molina, Daniel "Ligand and solvent effects in the formation and self-assembly of a metallosupramolecular cage." New Journal of Chemistry 41 (2017): 1179-1185. Teresa Corona; Lídia Ribas; Mireia Rovira; Erik R. Farquhar; Xavi Ribas; Kallol Ray; Anna Company "Characterization and Reactivity Studies of a Terminal Copper-Nitrene Species." Angewandte Chemie International Edition 55 (2016): 14005-14008. Oriol Planas; Christopher J. Whiteoak; Vlad Martin-Diaconescu; Ilaria Gamba; Josep M. Luis; Teodor Parella; Anna Company; Xavi Ribas "Isolation of Key Organometallic Aryl-Co(III) Intermediates in Cobalt-Catalyzed C(sp2)-H Functionalizations and New Insights into Alkyne Annulation Reaction Mechanisms." Journal of the American Chemical Society 138 (2016): 14388-14397. Serra i Parareda, Jordi; Parella Coll, Teodor; Ribas Salamaña, Xavi "Au(III)-aryl intermediates in oxidant-free C-N and C-O cross-coupling catalysis." Chemical Science 8 (2016): 946-952. Francisco Olmo; Miquel Costas; Clotilde Marín; Maria José Rosales; Rubén Martín-Escolano; Olaf Cussó; Ramón Gutierrez-Sánchez; Xavi Ribas; Manuel Sánchez-Moreno "Tetradentate polyamines as efficient metallodrugs for Chagas disease treatment in murine model." Journal of Chemotherapy (2016): 1-11. Rovira Coll, Mireia; Soler, Marta; Güell Costa, Imma; Wang, Ming Zheng; Gómez Martín, Laura; Ribas Salamaña, Xavi "Orthogonal Discrimination among Functional Groups in Ullmann-Type C-O and C-N Couplingss." Journal of Organic Chemistry 81 (2016): 7315-7325. Whiteoak, Christopher J.; Ribas, Xavi; Planas Fàbrega, Oriol; Company Casadevall, Anna; Ribas Salamaña, Xavi "A First Example of Cobalt-Catalyzed Remote C-H Functionalization of 8-Aminoquinolines Operating through a Single Electron Transfer Mechanism." Advanced Synthesis and Catalysis 358 (2016): 1679-1688. Soler, Marta; González-Bártulos, Marta; Figueras, Eduard; Massaguer, Anna; Feliu, Lidia; Planas, Marta; Ribas, Xavi; Costas, Miquel "Delivering aminopyridine ligands into cancer cells through conjugation to the cell-penetrating peptide BP16." Organic and Biomolecular Chemistry 14 (2016): 4061-4070. Soler, Marta; Feliu, Lidia; Planas, Marta; Ribas, Xavi; Costas, Miquel "Peptide-mediated vectorization of metal complexes: conjugation strategies and biomedical applications." Dalton Transactions 45 (2016): 12970-12982. Font, David; Canta, Mercè; Milan, Michela; Cussó, Olaf; Ribas, Xavi; Klein Gebbink, Robertus; Costas, Miquel "Readily accessible bulky iron catalysts exhibiting chirality dependent site selectivity in the oxidation of steroidal substrates." Angewandte Chemie International Edition 55 (2016): 5776-5779. Francisco Olmo; Olaf Cussó; Clotilde Marín; Maria José Rosales; Kristína Urbanová; Luise Krauth-Siegel; Miquel Costas; Xavi Ribas; Manuel Sánchez-Moreno "In vitro and in vivo identification of tetradentated polyamine complexes as highly efficient metallodrugs against Trypanosoma cruzi." Experimental Parasitology 164 (2016): 20-30. Cussó, Olaf; Cianfanelli, Marco; Ribas, Xavi; Klein Gebbink, Robertus; Costas, Miquel "Iron catalyzed highly enantioselective epoxidation of cyclic aliphatic enones with aqueous H2O2." Journal of the American Chemical Society 138 (2016): 2732-2738. Han, M.; Luo, Y.; Damaschke, B.; Gómez, L.; Ribas, X.; Jose, A.; Peretzki, P.; Seibt,M.; Clever, G. H "Light-controlled Interconversion between a Self-assembled Triangle and a Rhombicuboctahedral Sphere." Angewandte Chemie International Edition 55 (2016): 445-449. Planas, Oriol; Whiteoak, Christopher; Company, Anna; Ribas, Xavi "Regioselective Access to Sultam Motifs through Cobalt-Catalyzed Annulation of Aryl Sulfonamides and Alkynes using an 8-Aminoquinoline Directing Group." Advanced Synthesis and Catalysis 357 (2015): 4003-4012. Soler, M; Figueras, E; Serrano-Plana, J; González-Bártulos, M; Massaguer, A; Company, A; Martínez, MA; Malina, J; Brabek, V; Feliu, L; Planas, M; Ribas, X; and Costas, M "Design, preparation and characterization of Zn and Cu metallopeptides based on tetradentate aminopyridine ligands showing enhanced DNA cleavage activity." Inorganic Chemistry 54 (2015): 10542-10558. García-Simón, Cristina; Costas, Miquel; Ribas, Xavi "Metallosupramolecular receptors for fullerene binding and release." Chemical Society Reviews 45 (2015): 40-62. González-Bártulos, Marta; Aceves-Luquero, Clara; Qualai, Jamal; Cussó, Olaf; Martínez, Mª Angeles; Fernández de Mattos, Silvi; Menéndez, Javier A.; Villalonga, Priam; Costas, Miquel; Ribas, Xavi; Massaguer, Anna "Pro-Oxidant Activity of Amine-Pyridine-Based Iron Complexes Efficiently Kills Cancer and Cancer Stem-Like Cells." PLoS One 10 (2015): e0137800-. Marta Soler, Marta González, Eduard Figueras, Xavi Ribas, Miquel Costas, Anna Massaguer, Lidia Feliu, Marta Planas "Enzyme-triggered delivery of chlorambucil from conjugates based on the cell-penetrating peptide BP16." Organic and Biomolecular Chemistry 13 (2015): 1470-1480. Serra, Jordi; Whiteoak, Christopher J.; Acuña-Parés, Ferran; Font, Marc; Luis, Josep M.; Lloret-Fillol, Julio; Ribas, Xavi "Oxidant-Free Au(I)-Catalyzed Halide Exchange and Csp2-O Bond Forming Reactions." Journal of the American Chemical Society 137 (2015): 13389-13397. Cussó, Olaf; Ribas, Xavi; Lloret-Fillol, Julio; Costas, Miquel "Synergistic Interplay of a Non-Heme Iron Catalyst and Amino Acid Coligands in H2O2 Activation for Asymmetric Epoxidation of α-Alkyl-Substituted Styrenes." Angewandte Chemie International Edition 54 (2015): 2729-2733. Marc Font, Xavi Ribas "Pincerlike Cyclic Systems for Unraveling Fundamental Coinage Metal Redox Processes." Topics In Organometallic Chemistry 54 (2015): 269-306. García-Simón, Cristina; Gramage-Doria, Rafael; Raoufmoghaddam, Saeed; Parella, Teodor; Costas, Miquel; Ribas, Xavi; Reek, Joost N. H. "Enantioselective hydroformylation by a Rh-catalyst entrapped in a supramolecular metallocage." Journal of the American Chemical Society 137 (2015): 2680-2687. Engineering Homochiral Metal-Organic Frameworks by Spatially Separating 1D Chiral Metal-Peptide Ladders: Tuning the Pore Size for Enantioselective Adsorption "Kyriakos C. Stylianou, Laura Gomez, Inhar Imaz, Cristobal Verdugo-Escamilla, Xavi Ribas, Daniel Maspoch." Chemistry-A European Journal 21 (2015): 9964-9969. García-Simón, Cristina; Garcia-Borràs, Marc; Gómez, Laura; Parella, Teodor; Osuna, Sílvia; Juanhuix, Jordi; Imaz, Inhar; Maspoch, Daniel ; Costas, Miquel; Ribas, Xavi "Sponge-like molecular cage for purification of fullerenes." Nature Communications 5 (2014): -. Mireia Rovira; Marc Font; Ferran Acuña Parés; Teodor Parella; Josep M. Luis; Julio Lloret Fillol; Xavi Ribas "Aryl-Copper(III)-Acetylides as Key Intermediates in Csp2-Csp Model Couplings Under Mild Conditions." Chemistry-A European Journal 20 (2014): 10005-10010. Font, Marc; Acuña Parés, Ferran; Parella, Teodor; Serra, Jordi; Luis, Josep M.; Lloret-Fillol, Julio; Costas, Miquel; Ribas, Xavi "Direct observation of two-electron Ag(I)/Ag(III) redox cycles in coupling catalysis." Nature Communications 5 (2014): -. Mercè Canta; David Font; Laura Gómez; Xavi Ribas; Miquel Costas "The Iron(II) Complex [Fe(CF3SO3)2(mcp)] as a Convenient, Readily Available Catalyst for the Selective Oxidation of Methylenic Sites in Alkanes." Advanced Synthesis and Catalysis 356 (2014): 818-830. Xavi Ribas, Imma Güell "Cu(I)/Cu(III) catalytic cycle involved in Ullmann-type cross-coupling reactions." Pure and Applied Chemistry 86 (2014): 345-360. Marta Soler, Marta González, David Soriano-Castell, Xavi Ribas, Miquel Costas, Francesc Tebar, Anna Massaguer, Lidia Feliu, Marta Planas "Identification of BP16 as a non-toxic cell-penetrating peptide with highly efficient drug delivery properties." Organic and Biomolecular Chemistry 12 (2014): 1652-1663. Imma Güell, Xavi Ribas "Ligand-free Ullmann-type C-Heteroatom couplings under practical conditions." European Journal of Organic Chemistry (2014): 3188-3195. Olaf Cussó; Isaac Garcia-Bosch; David Font; Xavi Ribas; Julio Lloret-Fillol; Miquel Costas "Highly Stereoselective Epoxidation with H2O2 Catalyzed by Electron-Rich Aminopyridine Manganese Catalysts." Organic Letters 15 (2013): 6158-6161. Olaf Cussó; Isaac Garcia-Bosch; Xavi Ribas; Julio Lloret-Fillol; Miquel Costas "Asymmetric Epoxidation with H2O2 by Manipulating the Electronic Properties of Non-heme Iron Catalysts." Journal of the American Chemical Society 135 (2013): 14871-14787. Irene Prat, Anna Company, Teresa Corona, Teodor Parella, Xavi Ribas, Miquel Costas "Assessing the Impact of Electronic and Steric Tuning of the Ligand in the Spin State and Catalytic Oxidation Ability of the FeII(Pytacn) Family of Complexes." Inorganic Chemistry 52 (2013): 9229-9244. Cristina García-Simón; Marc Garcia-Borràs; Laura Gómez; Isaac Garcia-Bosch; Silvia Osuna; Marcel Swart; Josep M. Luis; Concepcio Rovira; Manuel Almeida; Inhar Imaz; Daniel Maspoch; Miquel Costas; Xavi Ribas "Self-assembled tetragonal prismatic molecular cage highly selective for anionic π-guests." Chemistry-A European Journal 19 (2013): 1445-1456. Irene Prat; Anna Company; Verònica Postils; Xavi Ribas; Lawrence Que Jr.; Josep M. Luis; Miquel Costas "The Mechanism of Stereospecific C-H Oxidation by Fe(PyTACN) Complexes. Bioinspired Non Heme Iron Catalysts Containing cis-Labile Exchangeable Sites." Chemistry-A European Journal 19 (2013): 6724-6738. Rovira, M.; Font, M.; Ribas, X. "Model Csp2/Csp3 Hurtley coupling catalysis that operates through a well-defined CuI/CuIII mechanism." ChemCatChem 5 (2013): 687-691. Laura Gómez, Mercè Canta, David Font, Irene Prat, Xavi Ribas, Miquel Costas "Regioselective Oxidation of Nonactivated Alkyl C−H Groups Using Highly Structured Non-Heme Iron Catalysts." Journal of Organic Chemistry 78 (2013): 1421-1433. Alicia Casitas, Xavi Ribas "The role of organometallic copper(III) complexes in homogeneous catalysis." Chemical Science 4 (2013): 2301-2318. Prat, Irene; Gómez, Laura; Canta, Mercè; Ribas, Xavi; Costas, Miquel "An Iron Catalyst for Oxidation of Alkyl C-H Bonds Showing Enhanced Selectivity for Methylenic Sites." Chemistry-A European Journal 19 (2013): 1908-1913. Prat, Irene; Font, David; Junge, Kathrin; Company, Anna; Ribas, Xavi; Beller, Mathias; Costas, Miquel "Fe(PyTACN)-Catalyzed cis-Dihydroxylation of Olefins with Hydrogen Peroxide." Advanced Synthesis and Catalysis 355 (2013): 947-956. Isaac Garcia‐Bosch; Zoel Codolà; Irene Prat; Xavi Ribas; Julio Lloret‐Fillol; Miquel Costas "Iron‐Catalyzed C-H Hydroxylation and Olefin cis‐Dihydroxylation Using a Single‐Electron Oxidant and Water as the Oxygen‐Atom Source." Chemistry-A European Journal 18 (2012): 13269-13273. Font, M.; Parella, T.; Costas, M.; Ribas, X. "Catalytic C-S, C-Se and C-P cross-coupling reactions mediated by a Cu(I)/Cu(III) redox cycle." Organometallics 31 (2012): 7976-7982. Isaac Garcia-Bosch, Xavi Ribas, Miquel Costas "Well-Defined Heterometallic and Unsymmetric M2O2 Complexes Arising from Binding and Activation of O2." European Journal of Inorganic Chemistry (2012): 179-187. Isaac Garcia-Bosch, Xavi Ribas, Miquel Costas "Electrophilic Arene Hydroxylation and Phenol O[BOND]H Oxidations Performed by an Unsymmetric μ-η1:η1-O2-Peroxo Dicopper(II) Complex." Chemistry-A European Journal 18 (2012): 2113-2122. Isaac Garcia-Bosch; Laura Gómez: Alfonso Polo; Xavi Ribas; Miquel Costas "Stereoselective epoxidation of alkenes with hydrogen peroxide using bipyrrolidine-based family of manganese complexes." Advanced Synthesis and Catalysis 354 (2012): 65-70. Prat, I.; Mathieson, J. S.; Guell, M.; Ribas, X.; Luis, J.M.; Cronin, L.; Costas, M. "Observation of Fe(V)=O using variable-temperature mass spectrometry and its enzyme-like C-H and C=C oxidation reactions." Nature Chemistry 3 (2011): 788-793. Garcia-Bosch, Isaac; Company, Anna; Cady, Clyde W.; Styring, Stenbjörn; Browne, Wesley R.; Ribas, Xavi; Costas, Miquel "Evidence for a Precursor Complex in C-H Hydrogen Atom Transfer Reactions Mediated by a Manganese(IV) Oxo Complex." Angewandte Chemie International Edition 50 (2011): 5648-5653. Schröder, K; Join, B; Amali, A; Junge, K; Ribas, X; Costas, M; Beller, M "A Biomimetic iron catalyst for the epoxidation of olefins with molecular oxygen at room temperature." Angewandte Chemie International Edition 50 (2011): 1425-1429. Company, A.; Prat, I; Frisch, J.R.; Mas-Ballesté, R.; Güell, M.; Juhász, G.; Ribas, X.; Münck, E.; Luis, J.M.; Que, L. Jr.; Costas, M. "Modeling the cis-Oxo-Labile Binding Site Motif of Non-Heme Iron Oxygenases: Water Exchange and Oxidation Reactivity of a Non-Heme Iron(IV)-Oxo Compound Bearing a Tripodal Tetradentate Ligand." Chemistry-A European Journal 17 (2011): 1622-1634. Casitas, A.; Canta, M.; Solà, M.; Costas, M.; Ribas, X. "Nucleophilic Aryl Fluorination and Aryl Halide Exchange Mediated by a CuI/CuIII Catalytic Cycle." Journal of the American Chemical Society 133 (2011): 19386-19392. Alicia Casitas, Nikolaos Ioannidis, George Mitrikas, Miquel Costas, Xavi Ribas "Aryl–O reductive elimination from reaction of well-defined aryl–CuIII species with phenolates: the importance of ligand reactivity†." Dalton Transactions 40 (2011): 8796-8799. Lauren M. Huffman, Alicia Casitas, Marc Font, Mercè Canta, Miquel Costas, Xavi Ribas, Shannon S. Stahl "Observation and Mechanistic Study of Facile CO Bond Formation between a Well-Defined Aryl-Copper(III) Complex and Oxygen Nucleophiles." Chemistry-A European Journal 17 (2011): 10647-10650. Garcia-Bosch, I.; Company, A.; Frisch, J.R.; Torrent-Sucarrat, M.; Cardellach, M.; Gamba, I.; Güell, M.; Casella, L.; Que, L. Jr.; Ribas, X.; Luis, J.M.; Costas, M. "O-2 Activation and Selective Phenolate ortho Hydroxylation by an Unsymmetric Dicopper mu-eta(1):eta(1)-Peroxido Complex." Angewandte Chemie International Edition 49 (2010): 2406-2409. Ribas, X.; Calle, C.; Poater, A.; Xifra, R.; Casitas, A.; Gómez, L.; Parella, T.; Benet-Buchholz, J.; Schweiger, A.; Mitrikas, G.; Solà, M.; Llobet, A.; Stack, T.D.P. "Facile C-H Bond Cleavage via a Proton-Coupled Electron Transfer Involving an Agostic C-H···CuII Interaction." Journal of the American Chemical Society 132 (2010): 12299-12306. Bruno,G.; Almeida,M.;Artizzu,F.; Dias,J.C.; Mercuri, M.L.; Pilia,L.; Rovira, C.; Ribas, X.;Serpec, A.; Deplano, P. " Innocence and noninnocence of the ligands in bis(pyrazine-2,3-dithiolate and -diselonate) d8-metal complexes. A theoretical and experimental study for the Cu(III), Au(III) and Ni(II) cases." Journal of the Chemical Society-Dalton Transactions 39 (2010): 4566-4574. Casitas,A.; King, A.E.;Parella, T.; Costas, M.;Stahl, S. S.; Ribas, X. "Direct observation of Cu(I)/Cu(III) redox steps relevant to Ullmann-type coupling reactions." Journal of the Chemical Society-Dalton Transactions 1 (2010): 326-330. King, A. E.; Huffman, L. M.;Casitas, A.;Costas, A.; Ribas,X.; Stahl, S. S. "Copper-catalyzed aerobic oxidative functionalization of an arene C-H bond: evidence for an aryl-copper(III)." Journal of the American Chemical Society 132 (2010): 12068-12073. Casitas,A.; Poater,A.; Solà. M.;Stahl,S. S.; Costas, M.;Ribas, X. "Molecular mechanism of acid-triggered aryl-halide reductive elimination in well-defined aryl-Cu(III)-halide species." Dalton Transactions 39 (2010): 10458-10463. Gómez, L.; Garcia-Bosch, I.; Company, A.; Benet-Buchholz,J,; Polo, A.; Sala,X.; Ribas, X.; Costas, M. "Stereospecific C-H oxidation with H2O2 catalyzed by a chemically robust site-isolated iron catalyst." Angewandte Chemie International Edition 48 (2009): 5720-5723. Company, A.; Feng, Y.; Güell, M.; Ribas, X.; Luis, J.M.; Que, L. Jr.; Costas, M. "Olefin-Dependent Discrimination Between Two Nonheme HO-FeV=O Tautomeric Species in Catalytic H2O2 Epoxidations." Chemistry-A European Journal 15 (2009): 3359-3362. Garcia-Bosch, I.; Ribas, X.; Costas, M. "A Broad Substrate-Scope Method for Fast, Efficient and Selective Hydrogen Peroxide-Epoxidation." Advanced Synthesis and Catalysis 351 (2009): 348-352. Company, A.; Roques, N.; Güell, M.; Mugnaini, V.; Gómez, L.; Datcu, A.; Imaz, I.; Solà, M.; Luis, J.M.; Veciana, J.; Ribas, X.; Costas, M. "Nanosized trigonal prismatic and antiprismatic Cu(II) coordination cages based on tricarboxylate linkers ." Journal of the Chemical Society-Dalton Transactions (2008): 1679-1682. Company, A.; Palavicini, S.; Garcia-Bosch, I.; Mas-Ballesté, R.; Que, L.; Rybak-Akimova, E.V.; Casella, L.; Ribas, X.; Costas, M. "Tyrosinase-Like reactivity in a cuIII2(µ-O)2 species." Chemistry-A European Journal 14 (2008): 3535-3538. Garcia-Bosch, I.; Company, A.; Fontrodona, X.; Ribas, X.; Costas, M. "Efficient Peracetic Acid Epoxidation Catalyzed by a Robust Manganese Catalyst Exhibiting Remarkable Selectivity." Organic Letters 10 (2008): 2095-2098. Company, A.; Gómez, L.; Fontrodona, X.; Ribas, X.; Costas, M. "A novel platform for modeling oxidative catalysts in non-heme iron oxygenases with unprecedent efficiency ." Chemistry-A European Journal 14 (2008): 5727-5731. Poater, A.; Ribas, X.; Cavallo, L.; Llobet, A.; Solà, M. "Complete Mechanism of σ* Intramolecular Aromatic Hydroxylation through O2 Activation by a Macrocyclic Dicopper(I) Complex." Journal of the American Chemical Society 130 (2008): 17710-17717. Company, A.; Gómez, L.; Guell, M.; Ribas, X.; Luis, J. M.; Lawrence Que, Jr.; Costas, M. "Alkane hydroxylation by a nonheme iron catalyst that challenges the heme paradigm for oxygenase action." Journal of the American Chemical Society 129 (2007): 15766-15767. Company, A.; Gomez, L.; Mas-Balleste, R.; Korendovych, I. V.; Ribas, X.; Poater, A.; Parella, T.; Fontrodona, X.; Benet-Buchholz, J.; Sola, M.; Que., L., Jr.; Rybak-Akimova, E. V.; Costas, M. "Fast O2 Binding at Dicopper Complexes Containing Schiff-Base Dinucleating Ligands." Inorganic Chemistry 46 (2007): 4997-5012. Company, A.; Jee, J.; Ribas, X.; Lopez-Valbuena, J.M.; Gómez, L.; Corbella, M.; Llobet, A.; Mahía, J.; Benet-Buchholz, J.; Costas, M.; van Eldik, R. " Structural and Kinetic Study of Reversible CO2 Fixation by Dicopper Macrocyclic Complexes. From Intramolecular Binding to Self-Assembly of Molecular Boxes." Inorganic Chemistry 46 (2007): 9098-9110. Gómez, L.; Garcia-Bosch, I.; Company, A.; Sala, X.; Fontrodona, X.; Ribas, X.; Costas, M. "Chiral manganese complexes with pinene appended tetradentate ligands as stereoselective epoxidation catalysts." Journal of the Chemical Society-Dalton Transactions 47 (2007): 5539-5545. Ritimukta Sarangi, Serena DeBeer George, Deanne Jackson Rudd, Robert K. Szilagyi, Xavi Ribas, Concepcio Rovira, Manuel Almeida, Keith O. Hodgson, Britt Hedman, Edward I. Solomon "Sulfur K-Edge X-ray Absorption Spectroscopy as a Probe of Ligand-Metal Bond Covalency: Metal vs Ligand Oxidation in Copper and Nickel Dithiolene Complexes." Journal of the American Chemical Society 129 (2007): 2316-2326. Gómez, L.; Company. A.; Fontrodona, X.; Ribas, X.; Costas, M. "Self-assembling of nanoscopic molecular rectangles, extended helicates and porous-like materials based on macrocyclic dicopper building blocks under fine supramolecular control." Chemical Communications 42 (2007): 4410-4412. Ribas, X.; Xifra, R.; Parella, T.; Poater, A.; Solà, M.; Llobet A. "Regiospecific C-H Activation: Reversible H/D Exchange Promoted by Cu(I) Complexes with Triazamacrocyclic Ligands." Angewandte Chemie International Edition 45 (2006): 2941-2944. Company, A.; Guell, M.; Popa, D.; Benet, J.; Parella, T.; Fontrodona, X.; Llobet, A.; Solà, M.; Ribas, X.; Luis, J. M.; Costas, M. "Redox-controlled molecular flipper based on a chiral cu complex." Inorganic Chemistry 45 (2006): 9643-9645. Costas, M.; Ribas, X.; Poater, A.; Balvuena, J.M.; Xifra, R.; Company, A.; Duran, M.; Solà, M.; Llobet, A.; Corbella, M.; Usón, M.A.; Mahía, J.; Solans, X.; Shan, X.; Benet-Buchholz, J. "Copper(II) hexaaza macrocyclic binuclear complexes obtained from the reaction of their Copper(I) derivates and molecular dioxygen ." Inorganic Chemistry 45 (2006): 3569-3581. Ribas, X.; Maspoch, D.; Wurst, K.; Veciana,J.; Rovira, C. "Coordination capabilities of a novel organic polychlorotriphenylmethyl monosulfonate radical." Inorganic Chemistry 45 (2006): 5383-5392. Xifra, R.; Ribas, X.; Llobet, A.; Poater, A.; Duran, M.; Solà, M.; Stack, T.D.P.; Benet-Buchholz, J.; Donnadieu, B.; Mahía, J.; Parella, T. "Fine tuning electronic properties of highly stable organometallic Cu(III) complexes containing monoanionic macrocyclic ligands." Chemistry-A European Journal 11 (2005): 5146-5156. Ribas, X.; Mas-Torrent, M.; Pérez-Benítez, A.; Dias, J.C.; Alves, H.; Lopes, E.B.; Henriques, R.T.; Molins, E.; Santos, I.C.; Wurst, K.; Foury-Leylekian, P.; Almeida, M.; Veciana, J.; Rovira, C. "Organic spin-ladders from TTF derivatives." Advanced Functional Materials 15 (2005): 1023-1035. Ribas, X.; Sironi, A.; Masciocchi, N.; Lopes, E.B.; Almeida, M.; Veciana, J.; Rovira, C. "Structural, Magnetic and Electrical Characterization of New Polycrystalline Phases of Nickel and Platinum-Doped [(DT-TTF)n][Au(mnt)2] (n = 1, 2)." Inorganic Chemistry 44 (2005): 2358-2366. Dias, J.C; Ribas, X.; Morgado, J.; Seiça, J.; Lopes, E.B.; Santos, I.C.; Henriques, R.T.; Almeida, M.; Wurst, K.; Foury-Leylekian, P.; Canadell, E.; Vidal-Gancedo, J.; Veciana, J.; Rovira, C. "Multistability in a family of DT-TTF organic radical based compounds (DT-TTF)4[M(L)2]3 (M = Au, Cu/ L = pds, pdt, bdt)." Journal of Materials Chemistry 15 (2005): 3187-3199. Dias, J.C.; Lopes, E.B.; Santos, I.C.; Duarte, M.T.; Henriques, R.T.; Almeida, M.; Ribas, X.; Rovira, C.; Veciana, J.; Foury-Leylekian, P.; Pouget,J.P.; Auban-Senzier, P.; Jérome, D. "Structural and Electrical Properties of (DT-TTF)2[Cu(mnt)2]." J. Phys. IV 114 (2004): 497-499. Lopes, E.B.; Dias, J.C.; Seiça, J.P.; Santos, I.C.; Morgado, J.; Henriques, R.T.; Almeida, M.; Ribas, X.; Wurst, K.; Veciana, J.; Rovira, C.; Foury-Leylekian, P. "The low and high temperature phase transitions in the family of compounds (DT-TTF)4[M(L)2]3 , M=Au, Cu and L= pds, pdt." J. Phys. IV 114 (2004): 537-539. Ribas, X.; Maspoch, D.; Dias, J.; Morgado, J.; Almeida, M.; Wurst, K.; Vaughan, G.; Veciana, J.; Rovira, C. "2D Layered coordination polymer based on an unusual mixed valence Cu(III)/Cu(I) bis-1,2-diselenolene compound." CrystEngComm 6 (2004): 589-592. Ribas, X.; Dias, J.; Morgado, J.; Wurst, K.; Almeida, M.; Parella, T.; Veciana, J.; Rovira, C. "Stepwise Construction of Oligomeric 1,2-Diselenolene Platinum(IV) Complexes." Angewandte Chemie International Edition 43 (2004): 4049-4052. Ribas, X.; Dias, J.; Molins, J.; Wurst, K.;Molins, E.; Ruiz, E.; Almeida, M.; Almeida, J.; Rovira, C. "Novel CuIII bis-1,2-dichalcogenene complexes with tunable 3D framework through alkaline cation coordination. A structural and theoretical study." Chemistry-A European Journal 10 (2004): 1691-1704. Mas-Torrent, M.; Hadley, P.; Ribas, X.; Rovira, C. "Temperature dependence of single-crystal Field Effect Transistors based on Dithiophene-Tetrathiafulvalene (DT-TTF)." Synthetic Metals 146 (2004): 265-368. Ribas, X.; Dias, J.; Morgado, J.; Wurst, K.; Santos, I.; Almeida, M.; Vidal-Gancedo, J.; Veciana, J.; Rovira, C. "Alkaline side-coordination strategy for the design of Nickel(II) and Nickel(III) bis(1,2-diselenolene) complex based materials." Inorganic Chemistry 43 (2004): 3631-3641. Mas-Torrent, M.; Durkut, M.; Hadley, P.; Ribas, X.; Rovira, C. "High Mobility of Dithiophene-tetrathiafulvalene Single Crystal Organic Field Effect Transistor." Journal of the American Chemical Society 126 (2004): 984-985. Mas-Torrent, M.; Hadley, P.; Bromley, S.T.; Ribas, X.; Tarrés, J.; Mas, M.; Molins, E.; Veciana, J.; Rovira, C. "Correlation Between Crystal Structure and Mobility in Organic Field-Effect Transistors Based on Single Crystals of Tetrathiafulvalene Derivatives." Journal of the American Chemical Society 126 (2004): 8546-8553. Ribas, X.; Mas-Torrent, M.; Rovira, C.; Veciana, J.; Dias, J.; Alves, H.; Lopes, E.B.; Almeida, M.; Wurst, K. "Molecular compounds based on DT-TTF and Au(cdc)2 complex. Structural, magnetic and electrical properties." Polyhedron 22 (2003): 2415-2422. Dias, J.; Morgado, J.; Alves, H.; Lopes, E.B.; Santos, I.C.; Duarte, M.T.; Henriques, R.T.; Almeida, M.; Ribas, X.; Rovira, C.; Veciana, J. "Magnetic and electrical properties of (DT-TTF)4[Au(pds)2]3." Polyhedron 22 (2003): 2447-2452. Mas-Torrent, M.; Turner, S.S.; Wurst, K.; Vidal-Gancedo, J.; Ribas, X.; Veciana, J.; Day, P.; Rovira, C. "Bulk Spontaneous Magnetization in the New Radical Cation Salt TM-TTF[Cr(NCS)4(isoquinoline)2] (TM-TTF = Tetramethyltetrathiafulvalene)." Inorganic Chemistry 42 (2003): 7544-7549. Ribas, X.; Dias, J.; Morgado, J.; Wurst, K.; Almeida, M.; Veciana, J.; Rovira, C. "Novel Cu(III) bis-1,2-diselenolene complex with a highly extended 3D framework through Na+ coordination." CrystEngComm 4 (2002): 564-567. Ribas, X.; Jackson, D.A.; Donnadieu, B.; Mahía, J.; Parella, T.; Xifra, R.; Hedman, B.*; Hodgson, K.O.*; Llobet, A.*; Stack, T.D.P. "Aryl C-H activation by cuII to form an organometallic aryl-CuIII species: a novel twist on copper disproportionation." Angewandte Chemie International Edition 41 (2002): 2991-2994. Fusi, V.; Llobet, A.; Mahía, J.; Micheloni, M.; Paoli, P.; Ribas, X.; Rossi, P. "A new Cu(I) model complex that mimicks the cresolase reaction of tyrosinase. Crystal structure of its oxygenated Cu(II) complex." European Journal of Inorganic Chemistry (2002): 987-990. Ribas, R.; Donnadieu, B.; Jackson, D.; Hodgson, K.O.; Hedman, B.; Stack, T.D.P.; Llobet, A. "Aryl-Cu(III) complexes: an intermediate in aromatic hydroxylation." Journal of Inorganic Biochemistry 86 (2001): 399-399.
Cusso, Olaf; Ribas, Xavi; Costas, Miquel "Biologically Inspired Non-Heme Iron-Catalysts for Asymmetric Epoxidation; Design Principles, Strategies and Perspectives." Chemical Communications 51 (2015): 14285-14298.