1. Tema 1. Bioinspired Oxidation Reactions. Principles. Active Species. Fundamental Considerations for C-H and C=C Oxidation. Alcohol Oxidation. Sulfide oxidation.
2. Tema 2. P450 and Model systems. Description of P450. Iron and Manganese Based Models. Mechanistic considerations on P450 and related. The rebound mechanism. Radical clocks. Two-state Reactivity scenarios. Selective C-H Oxidation at Metalloprophyrins. Catalysis at Ru based metalloporphyrins.
3. Tema 3. Asymmetric oxidations at salen type of complexes. Discovery and Development. Substrate scope and Limitations. Mechanistic Considerations.
4. Tema 4. Non-Heme Iron oxygenases. Fe(III) based enzymes. Fe(II) based enzymes. Rieske Dioxygenases. Alfa-Ketoglutarate dependent enzymes. MMO and Related. Reaction Mechanisms
5. Tema 5. Bioinspired oxidations at non-heme iron sites. Part 1. Fenton Chemistry. Gif Chemistry. Metal-based oxidants
6. Tema 6. Bioinspired Oxidations at Non-heme Iron Catalysts. Olefin Oxidation. Epoxidation. Cis-dihydroxylation. Selected systems. Mechanisms
7. Tema 7. Bioinspired Oxidations at Non-heme Iron Catalysts. C-H oxidations. Free-Radical transformations. Metal-centered oxidations. The PDP system and Related.
8. Tema 8. Bioinspired oxidations at Mn complexes. Epoxidations with the TMTACN system. Stack systems. Cis-dihydroxylation with Mn complexes. C-H Oxidations. Supramolecular aproaches. Technologically relevant Oxidations.
9. Tema 9. Bioinspired Oxidations at Copper Sites. Mononuclear Cu oxigenases. Dinuclear Cu oxigenases. Tyrosinase. Galactose Oxidase. Models for Tyrosinase. Models for GO. Alcohol Oxidation with GO models.
10. Tema 10. Water Oxidation. The PhII. Mn models. Ru Models. Ir models. Co systems. Fe Model. Mechanisms.
11. Tema 11. Oxidation reactions at supramolecular systems. Principles of Supramolecular catalysis. The problem of product inhibition. Porphyrin systems. The crabtree system. Collman systems. Preceeding catalysts.
12. Tema 12. The chemistry of the Fe(IV)=O
13. Tema 13. Supramolecular catalysis
14. Tema 14. Evolution and synthetic applications of the Heck-Matsuda reaction
15. Tema 15. Sonogashira reactions: synthesis of alkynes
16. Tema 16. Applications of Palladium-catalyzed coupling reactions in the pharmaceutical, agrochemical, and fine chemical industries